Hosts Brazil booked their place in the Quarter Finals with a win over Chile but had to rely on a penalty shootout.
Gonzalo Jara, recently released by Nottingham Forest, had the unenviable role of having to score the deciding penalty but his spot-kick hit the post and away to send Brazil through.
David Luiz, Marcelo and Neymar all netted from twelve yards for El Selecao while Maurico Panilla, Alexis Sanchez and Charles Aranguiz could not convert for Chile.
Paris Saint-Germain’s latest signing Luiz kneed the Brazilians in front 18 minutes in after Thiago Silva headed on Neymar’s corner for a simple finish for his new teammate.
Sanchez leveled the scores after 32 minutes when Brazil lost the ball cheaply from a throw in in their own half. Sanchez slotted home past Julio Cesar with ease after being given the time and space by the Brazilian back line.
Chile almost spoiled the party in the last minute of extra time but Pinilla could only hit the bar with a fierce drive in the dying seconds.
Brazil thought they had a winner ten minutes into the second half when Hulk shinned in an effort but after consideration from his linesman, Howard Webb ruled that the Zenit man controlled the ball with his arm.
Hulk also should have made it 2-1 to Brazil seven minutes before the end but had his shot brilliantly saved by Claudio Bravo.
The two teams had to settle for penalties though and it was Brazil who would book themselves a spot in the last eight.